Compact Groups are excellent laboratories to test the importance of interaction for triggering nuclear activity. Their high galaxy densities, similar to those observed in cluster cores, together with their low velocity dispersions maximize the chance of encounters. Gravitational interaction between their members it is clearly shown by morphological and kinematical perturbations, the presence of intergalactic gas emission in X-rays , the existence of tidal features such as tails or shells and the perturbed distribution of molecular and atomic gas. To carry out this work we need a large enough well defined sample of groups. Hence, we have defined a complete sample of Compact Groups obtained from the list of 92 groups with concordant redshift in the catalog by Hickson. The catalog can be considered complete until mu<=4.4 and the z distribution also shows a cutoff at about z=0.045, which is the limit that we will adopt here. We have therefore selected all the groups with mu<=4.4 and z<=0.045, which gives a well defined statistically complete sample of 65 groups. We will present optical spectroscopy for 42 galaxies belonging to the sample and their preliminary nuclear classification by us diagram and the [NII]/Ha ratio to distinguish between photoionization produced by OB stars (HII-region) or by a non-thermal continuum (AGN). Adding the 68 galaxies, belonging to the sample and classified by Coziol et al (2004), we have 110 analized galaxies.