At all stages of their evolution, low-and intermediate-mass stars exhibit the signatures of complex physical processes that require challenging modelling beyond canonical (or standard) stellar theory (by canonical we refer to the modelling of non-rotating, non-magnetic stars, in which convection is the only mechanism that drives mixing in stellar interiors). In particular, spectroscopic observations show clear signatures of extra-mixing on the upper Red Giant Branch. To explain these abundances anomalies, Charbonnel & Zahn (2007) identified thermohaline mixing as the dominating process that governs the photospheric composition of low-mass bright giant stars. We present the predictions of our stellar models computed with the code STAREVOL, taking into account this mechanism together with rotational mixing. We discuss the effects of these processes on the chemical properties of stars (Charbonnel & Lagarde 2010), and on the corresponding yields for 3He in the context of the so-called the "3He problem".